Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Paper | Regular issue | Vol 104, No. 10, 2022, pp.1770-1781
Published online, 9th August, 2022
DOI: 10.3987/COM-22-14720
Direct Arylation of Furoxan Using Potassium Aryltrifluoroborates

Chenlu Dong, Masahiko Hayashi, and Ryosuke Matsubara*

*Department of Chemistry , Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan

Abstract

Direct arylation of a furoxan ring with potassium aryltrifluoroborates is proposed. A series of aryl-substituted furoxan derivatives have been constructed through the formation of a new C−C bond via a radical pathway. The plausible reaction mechanism is proposed based on the DFT-calculation study.