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Paper | Special issue | Vol 97, No. 1, 2018, pp.211-217
Published online, 17th November, 2017
DOI: 10.3987/COM-17-S(T)3
Polymeric Silver(I) Complexes Based on Bidentate Imidazoline-2-thiones. Synthesis and Crystal Structures

Barbara Rietzler, Gerhard Laus, Klaus Wurst, Thomas Gelbrich, Sven Nerdinger,* Erwin Schreiner, and Herwig Schottenberger

*Sandoz GmbH, Biochemiestrasse 10, 6250 Kundl, Austria

Abstract

The bidentate ligand 1,6-bis(1-methylimidazol-2-ylthio)hexane or its hexafluoride salt reacted with silver(I) triflate, nitrate or oxide, respectively, to give the corresponding polymeric silver(I) complexes. Three crystal structures have been determined and showed linear and cyclic motifs.