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Paper | Regular issue | Vol 92, No. 12, 2016, pp.2201-2212
Published online, 16th November, 2016
DOI: 10.3987/COM-16-13584
Synthesis of β-Glycosyl Formamides Through N-Glycosylation of Unprotected Carbohydrates

Yoshiyasu Ichikawa,* Akihito Matsukawa, Mitsutoshi Maeda, Yumiko Tomita, Rika Mimura, Ayumi Kitamori, Hiyoshizo Kotsuki, Keiji Nakano, and Toshiya Masuda

*Faculty of Science, Kochi University, 2-5-1, Akebono-cho, Kochi 780-8520, Japan

Abstract

Two new synthetic routes involving N-glycosylation of unprotected carbohydrates were developed for the preparation of β-glycosyl formamides. Using this protocol, D-glucose, D-xylose, D-galactose and D-maltose were transformed to their corresponding β-glycosyl formamides.