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Paper | Special issue | Vol 95, No. 1, 2017, pp.243-250
Published online, 1st August, 2016
DOI: 10.3987/COM-16-S(S)10
Total Synthesis of Fargesine Using a Platinum-Catalyzed Intramolecular Friedel-Crafts-Type C–H Coupling–Allylic Amination Cascade

Yuito Tanaka, Yuta Suzuki, Yasumasa Hamada, and Tetsuhiro Nemoto*

*Pharmaceutical Chemistry, Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1 Inohana, Chuo, Chiba, Japan

Abstract

Total synthesis of fargesine was described herein. The synthesis was based on the platinum-catalyzed intramolecular Friedel-Crafts-type C–H coupling–allylic amination cascade to construct the 3,4-fused tricyclic indole skeleton.