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Communication | Special issue | Vol 95, No. 1, 2017, pp.158-166
Published online, 29th December, 2016
DOI: 10.3987/COM-16-S(S)43
Catalytic Aromatic Borylation via in situ-Generated Borenium Species

Fumiya Kitani, Ryo Takita,* Tatsushi Imahori, and Masanobu Uchiyama*

*RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan


We have developed a catalytic direct borylation of arenes via in situ-generated borenium species. The choice of appropriate Lewis base was crucial to achieve the catalytic system. Electron-rich arenes were borylated in a regioselective manner.