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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Special issue | Vol 95, No. 2, 2017, pp.753-760
Published online, 29th December, 2016
Published online, 29th December, 2016
DOI: 10.3987/COM-16-S(S)78
■ Palladium- and Norbornene-Catalyzed Synthesis of Highly Functionalized Thiophenes: The Remarkable Effect of Electron-Poor Olefins as Ligand
Nicola Della Ca’,* Elena Motti, Giovanni Maestri, and Max Malacria*
*ICSN CNRS UPR2301, 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette, France
Abstract
Highly functionalized heterocyclic compounds were synthesized by palladium and norbornene catalysis starting from ortho-substituted aryl iodides, aryl bromides and 3,4-ethylenedioxythiophene. The addition of methyl cinnamate to the reaction mixture was found to be crucial in order to obtain selectively the unsymmetrical product.
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