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Short Paper | Special issue | Vol 95, No. 1, 2017, pp.568-574
Published online, 20th September, 2016
DOI: 10.3987/COM-16-S(S)21
Palladium-Catalyzed Cross-Coupling of Aryl Chlorides with Arylsilatranes

Yutaro Yamamoto, Alexandre Baralle, Anaïs Godefroy, Kei Murakami, Hideki Yorimitsu,* and Atsuhiro Osuka

*Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan

Abstract

The cross-coupling reactions of arylsilatranes with readily available and inexpensive aryl chlorides were carried out in toluene/THF at 100 ºC for 3 h in the presence of tetrabutylammonium fluoride as an activator for smooth transmetalation and catalytic amounts of palladium(II) acetate and XPhos.