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Short Paper | Special issue | Vol 93, No. 2, 2016, pp.762-769
Published online, 30th October, 2015
DOI: 10.3987/COM-15-S(T)32
Unsymmetrical Phthalocyanines With One TTF unit and Octylthio or Octylsulfonyl Groups: Their Optical and Electrochemical Properties

Takeshi Kimura,* Jasmin Kang, and Shidsuko Nakajo

*Center for Instrumental Analysis, Iwate University, 4-3-5 Ueda, Morioka, Iwate 020-8551, Japan


Unsymmetrical phthalocyanines fused with a TTF unit and six octylthio or six octylsulfonyl groups were prepared by the reaction of a mixture of phthalonitrile fused with a TTF unit and 4,5-di(octylthio)- or 4,5-di(octyl- sulfonyl)phthalonitrile. The optical and electrochemical properties of the products were determined by UV-vis absorption spectra, cyclic voltammetry, and ESR spectra.