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■ Environmental Friendly Synthesis of Bis-Perfluoropyridine and Pyrimidine in Water

Reza Ranjbar-Karimi* and Aliyeh Khaje-Khezri

*Department of Chemistry, Vali-Asr University, Islamic Republic of Iran, 7713936417, Iran

Abstract

An easy, efficient and simple approach for the synthesis of some perfluoropyridine and pyrimidine derivatives by reaction of pentafluoropyridine and tetrafluoropyrimidine with mono and bidentate N-nucleophiles in the presence of potassium carbonate in water as a green solvent, at room temperature is reported. The structures of some products were unambiguously confirmed by X-ray crystallography.