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Paper | Regular issue | Vol 89, No. 2, 2014, pp.399-412
Published online, 6th January, 2014
DOI: 10.3987/COM-13-12896
■ Synthesis of 2-Deoxy-L-ribose via Palladium(II)-Catalyzed Cyclization

Masahiro Miyazawa,* Erika Akita, Kazusi Onda, Magsarjav Narantsetseg, Haruna Minabe, Hajime Yokoyama, and Yoshiro Hirai*

*Department of Chemistry, Graduate School of Science and Engineering, Toyama University, Gofuku 3190, Toyama 930-8555, Japan

Abstract

We present a total synthesis of 2-deoxy-L-ribose through intramolecular palladium(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as the key step.