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Obituary
Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Communication | Special issue | Vol 88, No. 2, 2014, pp.911-917
Published online, 14th August, 2013
Published online, 14th August, 2013
DOI: 10.3987/COM-13-S(S)61
■ Synthesis of p-tert-Butylcalix[4]thiacrowns Exhibiting Sulfur Number-Dependent Complexation with Mercury(II) Ion
Tatsuya Takimoto,* Hirohito Tsue, Hiroki Takahashi, Rui Tamura, and Hideaki Sasaki
*Faculty of Pharmaceutical Sciences, Kobe Gakuin University, 1-1-3 Minatojima, Chuo-ku, Kobe 650-8586, Japan
Abstract
A novel synthetic pathway to calix[4]thiacrowns 3 and 4 has been developed. NMR studies revealed that the complexation behavior of 3 and 4 with mercury(II) ion was controlled by the number of sulfur atoms involved in the thiacrown moiety.
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