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Short Paper | Special issue | Vol 88, No. 2, 2014, pp.1519-1526
Published online, 21st August, 2013
Published online, 21st August, 2013
DOI: 10.3987/COM-13-S(S)54
■ Iodoetherification of Conformationally Restricted Dienyl Alcohols: Unexpected Formation of Oxocenes by 8-endo-mode Oxacyclizations
Kristen L. Stoltz, Andrea-Nekane R. Alba, Frank E. McDonald,* Marika B. Wieliczko, and John Bacsa
*Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, U.S.A.
Abstract
Iodine-promoted oxacyclizations of a family of conformationally restricted dienyl alcohols consistently afford oxocenes, arising from 8-endo-mode cyclizations.
The Japan Institute of Heterocyclic Chemistry 503 1-1-7 Motoakasaka, Minato-ku, Tokyo 107-0051, Japan
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