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Review | Regular issue | Vol 87, No. 4, 2013, pp.763-805
Published online, 21st February, 2013
DOI: 10.3987/REV-12-762
Recent Progress in Organocatalytic Asymmetric Halocyclization

Kenichi Murai and Hiromichi Fujioka*

*Graduate School of Pharmaceutical Science, Osaka University, 1-6 Yamadaoka, Suita, Osaka 560-0871, Japan

Abstract

In this review, recent progress made in the development of organocatalytic asymmetric halocyclization reactions that form heterocyclic compounds is described. New reactions and their mechanistic features are discussed in the context of an outline based on catalyst types, including biscinchona alkaloids, amino ureas, amino thioureas, amino thiocarbamates, chiral phosphoric acids, and trisimidazolines.