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Communication | Regular issue | Vol 85, No. 7, 2012, pp.1603-1606
Published online, 17th May, 2012
DOI: 10.3987/COM-12-12492
[1,2]-Wittig Rearrangement of Aromatic Heterocycles

Jingyue Yang, Apiwat Wangweerawong, and Gregory B. Dudley*

*Department of Chemistry and Biochemistry, Florida State University, 12 Varsity Way, MC 4390, Tallahassee, U.S.A.

Abstract

Anionic rearrangement of diverse heteroaryl ethers is reported. In many cases, directed metallation followed by formal [1,2]-Wittig rearrangement provides heteroaryl carbinols in good yield.