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Review | Regular issue | Vol 85, No. 8, 2012, pp.1795-1819
Published online, 16th April, 2012
DOI: 10.3987/REV-12-736
Transition-Metal-Catalyzed Borylation of Organic Halides with Hydroboranes

Miki Murata*

*Department of Materials Science and Engineering, Kitami Institute of Technology, Koen-cho 165, Kitami, Hokkaido 090-8507, Japan


Metal-catalyzed cross-coupling reaction of B–H compounds provides a direct method for conversion of C–X bonds to C–B bonds. Dialkoxyboranes are excellent boron sources in the borylation of aryl, 1-alkenyl, allyl or benzyl halides or pseudohalides. These reactions tolerate large number of functional groups and proceeds with excellent yields, thereby allowing the simple, convenient, and elegant preparation of functionalized C–B compounds.