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Review | Special issue | Vol 84, No. 1, 2012, pp.209-221
Published online, 18th August, 2011
DOI: 10.3987/REV-11-SR(P)6
Copper-Catalyzed Domino Reaction of Heteroallenes towards Benzo-Heterocycle Compounds

Fei Wang, Peng Zhao, and Chanjuan Xi*

*Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China


The present review summarizes information on the copper-catalyzed reaction of heteroallenes, including carbodiimides, isothiocyanates, and carbon disulfide, with o-halobenzenamines or o-halophenols or o-halobenzamides for constructing benzo-heterocycle compounds via domino nucleophilic addition/cyclization reactions.