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Communication | Special issue | Vol 84, No. 1, 2012, pp.333-337
Published online, 22nd July, 2011
DOI: 10.3987/COM-11-S(P)42
Preparation and Optical and Electrochemical Properties of Unsymmetrical Phthalocyanines with One or Two TTF Units

Takeshi Kimura,* Nobuhiro Takahashi, Tomoyuki Tajima, and Yutaka Takaguchi

*Center for Instrumental Analysis, Iwate University, 4-3-5 Ueda, Morioka, Iwate 020-8551, Japan


Unsymmetrical phthalocyanines with one or two TTF units were obtained by treating mixed 3,6-dioctyltetrathiafluvalenophthalonitrile and 4,5-dioctoxyphthalonitrile with Li in n-hexanol. Their optical and electrochemical properties were examined by UV-vis spectroscopy and cyclic voltammetry.