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Paper | Regular issue | Vol 83, No. 3, 2011, pp.555-570
Published online, 26th January, 2011
DOI: 10.3987/COM-10-12115
Friedel-Crafts Reactions of Vinylaziridine Linked to an Ester Group

Hisashi Takada, Eiko Yasui, Yui Sahara, Yūki Chinen, Hirotoshi Tanaka, Yusuke Morita, Chihiro Kobiki, Daiki Narisawa, Megumi Mizukami, Masaaki Miyashita, and Shinji Nagumo*

*Department of Applied Chemistry, Faculty of Engineering, Kogakuin University, Nakano 2665-1, Hachioji, Tokyo, 192-0015, Japan


Intermolecular Friedel-Crafts reactions of vinylaziridines 11, 12, 15, 16 and 20 linked to an ester with various benzene derivatives occurred at the C4 position selectively to afford 5-amino-4-aryl-2-hexenoate derivatives in good yields.