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Review | Regular issue | Vol 83, No. 2, 2011, pp.247-273
Published online, 19th November, 2010
DOI: 10.3987/REV-10-681
Development of Trialkyl(2-indolyl)borates as Potential Synthetic Intermediates

Minoru Ishikura*

*Faculty of Pharmaceutical Sciences, Health Sciences University of Hokkaido, Ishikari-Tobetsu, Hokkaido 061-0293, Japan

Abstract

This account deals with our investigation of the reaction and synthetic use of indolylborates as versatile synthetic tools; 1) palladium-catalyzed cross-coupling reaction and its use for the synthesis of indole alkaloids and 2) intramolecular alkylmigration in indolylbotrates for the construction of highly elaborate indole derivatives.