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Obituary
Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Paper | Regular issue | Vol 81, No. 7, 2010, pp.1661-1667
Published online, 31st May, 2010
Published online, 31st May, 2010
DOI: 10.3987/COM-10-11965
■ Synthesis, Structure and Electrochemical Behavior of a Novel Redox-Active Thiacalix[4]arene-Tetrathiafulvalene Assembly
Bang-Tun Zhao,* Wen-Bo Guo, and Pu-Zhou Hu
*No. 71, Longmen Road, Department of Chemistry, Luoyang Normal University, Luoyang 471022, Henan Province, China
Abstract
A novel redox-active thiacalix[4]arene-tetrathiafulvalene assembly 5 was carried out through triethyl phosphite-mediated cross-coupling of the corresponding two 1,3-dithiole-2-(thi)ones (3 and 4). The structure of thiacalix[4]arene-tetrathiafulvalene assembly 5 was identified by X-ray diffraction analysis. Meanwhile, the preliminary electrochemical properties of 5 was investigated by cyclic voltammetry (CV) and two one-electron quasi-reversible waves with redox potentials are observed.
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