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Paper | Special issue | Vol 82, No. 2, 2010, pp.1229-1238
Published online, 20th August, 2010
DOI: 10.3987/COM-10-S(E)64
Preparation and Electrochemical Properties of Phthalocyaninato Titanium (IV) and Porphyrinato Titanium (IV) Benzenedichalcogenolates

Takeshi Kimura,* Kaori Amano, Arata Yamamoto, and Toshiharu Namauo

*Center for Instrumental Analysis, Iwate University, 4-3-5 Ueda, Morioka, Iwate 020-8551, Japan


The reaction of phthalocyaninato titanium (IV) oxides with benzenedithiol or benzenediselenol produced the corresponding complexes with titanium-sulfur or titanium-selenium bonds. Tetraphenylporphyrinato titanium (IV) benzenedichalcogenolates were obtained by the similar procedure. Their optical and electrochemical properties were determined by UV-vis spectroscopy and cyclic voltammetry.