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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Paper | Regular issue | Vol 78, No. 6, 2009, pp.1523-1539
Published online, 12th March, 2009
Published online, 12th March, 2009
DOI: 10.3987/COM-09-11674
■ Structure and Conformation of Photosynthetic Pigments and Related Compounds. 13. Identification of Localized Vibrational Modes in Chlorophyll A Derivatives
Mathias O. Senge*
*School of Chemistry, SFI Tetrapyrrole Laboratory, Trinity College Dublin, Dublin 2, Ireland
Abstract
A Resonance Raman investigation of chlorophyll a and meso-chlorinated and ring V hydroxylated derivatives and pheophytins reveals localized vibrational modes in the chlorophyll series. Both chlorination and hydroxylation give rise to changes in both band intensity and frequency throughout the spectrum. Chlorination affects mainly the core sensitive bands with CaCm and CaN character. Hydroxylation leads to changes in the carbonyl and ring V associated bands. Small, but real spectral differences were found between the 10-epimers.
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