Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Special issue | Vol 77, No. 1, 2009, pp.211-215
Published online, 7th August, 2008
DOI: 10.3987/COM-08-S(F)36
Pd(II)-Catalyzed Cyclization to Ether and Its Application to the Synthesis of the trans-Fused Polyether Core

Hajime Yokoyama, Satoshi Nakayama, Masayuki Murase, Masahiro Miyazawa, Seiji Yamaguchi, and Yoshiro Hirai*

*Department of Chemistry, Graduate School of Science and Engineering, Toyama University, Gofuku 3190, Toyama 930-8555, Japan


We employed an iterative Pd(II)-catalyzed cyclization reaction to ether from tri-O-acetyl-D-glucal to synthesize trans-fused polyethers. This approach should be applicable to synthesize the core structure of marine ladder toxins.