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Note | Special issue | Vol 77, No. 1, 2009, pp.587-593
Published online, 10th July, 2008
DOI: 10.3987/COM-08-S(F)19
Catalytic Asymmetric Intramolecular Allylation of Aldehyde

Tomohiro Sato and Kiyoshi Tomioka*

*Graduate School of Pharmaceutical Sciences, Kyoto University, 46-29 Yoshida-shimoadachi-machi, Sakyo-ku, Kyoto 606-8501, Japan


The intramolecular asymmetric allylation of aldehydes was catalyzed by a combination of pyrrolidine derivatives and Pd(0) to give 5-exo-cyclized aldehyde with fair ee in good yield.