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Communication | Special issue | Vol 25, No. 1, 1987, pp.109-111
Published online, 1st January, 1970
DOI: 10.3987/S-1987-01-0109
Regioselective Effects of the Allylic Heteroatoms in 1,3-Dipolar Cycloaddition of Nitrones to Several Allyl Derivativea

Yoshinobu Inouye, Satomi Niwayama, Tomonori Okada, and Hiroshi Kakisawa

*Department of Chemistry, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba-shi, Ibaraki, 305-8571, Japan

Abstract

Further evidences that the allylic oxygen atom affects the regioselectivity in 1,3-dipolar cycloaddition of nitrones highly toward to produce 4-alkoxymethylisoxazolidines were presented. The selectivity was unaffected by the geometry of dipolarophiles.