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Communication | Special issue | Vol 17, No. 1, 1982, pp.125-138
Published online, 1st January, 1970
DOI: 10.3987/S-1982-01-0125
Photochemistry of Azoles, Part VII. Photosolvolysis of Alkylmercaptoazoles.An Application to Some Acyclic Monoterpene Derivatives

Shigeo Iwasaki*

*Institute of Applied Microbiology, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8567, Japan

Abstract

Salts derived from 2-alkylmercapto-1-methylimidazoles 1b-e and 3-alkylmercapto-4-methyl-1,2,4-triazoles 2b-d have been found to undergo photochemical heterolytic fission of the S-alkyl bond in aqueous or methanolic solution to give solvolysis-type products.