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Communication | Special issue | Vol 15, No. 1, 1981, pp.251-254
Published online, 1st January, 1970
DOI: 10.3987/S-1981-01-0251
Synthesis of Adamantane Derivatives. 51. Synthesis of 2,4-Diazabridged-noradamantane, -protoadamantane, and -adamantane Derivatives via Intramolecular 1,3-Dipolar Cycloadditions

Tadashi Sasaki,* Shoji Eguchi, and Takanori Suzuki

*Department of Applied Chemistry, Faculty of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan

Abstract

N-Acyl-N’-methyl-2,4-diaza-bridged noradamantane (4), -protoadamantane (7), and -adamantane derivatives (10a,b) were obtained via intramolecular 1,3-dipolar cycloadditions of the corresponding C-bicycloalkenylazomethine imines (3, 6, 9a and 9b).