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Communication | Special issue | Vol 15, No. 1, 1981, pp.213-223
Published online, 1st January, 1970
DOI: 10.3987/S-1981-01-0213
Synthesis and Deuteration of Some Halogenoquinolizinium Bromides

Georgine M. Sanders,* Marinus van Dijk and Henk C. van der Plas

*Laboratory of Organic Chemistry, Agricultural University, De Dreijen 5, 6703 BC Wageningen, The Netherlands


Syntheses and 1H-nmr spectra are reported for the hitherto unknown 1-bromo-, 3-bromo-, 4-bromo-, 2-chloro-, 4-chloro-, 1,2-dibromo-, 3,4-dibromo- and 2,7-dibromoquinolizinium bromide. These compounds, quinolizinium bromide, 1-hydroxy-, 2-hydroxy-, 3-hydroxy-, 2-piperidino- and 2-diethylaminoquinolizinium bromide and 2- and 4-quinolizone were deuterated by heating with D2O (Table I).