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Communication | Special issue | Vol 10, No. 1, 1978, pp.185-198
Published online, 1st January, 1970
DOI: 10.3987/S-1978-01-0185
Neighboring Group Participation in Peptide Synthesis by the Use of Arylsulfonates of N-Hydroxyazoles and Related Compounds — Tautomeric Effect

Kusuo Horiki* and (in part) Atsuko Murakami

*Shionogi Research Laboratories, Shionogi & Co. Ltd., Fukushima-ku, Osaka 553-0002, Japan


The present paper deals with some attempt of the mechanistic elucidation an peptide bond formation using several arylsulfonates of N-hydroxy compounds and describes the important role of neighboring group involved in the N-hydroxy compounds in peptide synthesis.