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Communication | Special issue | Vol 11, No. 1, 1978, pp.235-242
Published online, 1st January, 1970
DOI: 10.3987/S(N)-1978-01-0235
Synthesis of Adamantane Derivatives. 44. Facile Synthesis of Some Homoadamantano[4,5]fused Heterocycles by the 1,3-Dipolar Cycloaddition and the Hoch-Campbell Reaction

Tadashi Sasaki,* Shoji Eguchi, and Soji Hattori

*Faculty of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan

Abstract

Homoadamantano[4,5]fused heterocycles 2, 3, 5 and 7 were obtained by the 1,3-dipolar cycloadditions of homoadamant-4-ene (1), and 2’-substituted homoadamantano[4,5-b]aziridines 9a-c were obtained by the Hoch-Campbell reaction of homoadamantan-4-one oxime (8).