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Communication | Special issue | Vol 11, No. 1, 1978, pp.219-226
Published online, 1st January, 1970
DOI: 10.3987/S(N)-1978-01-0219
Thiabenzenes X. Possible Roles for Sulfurane Intermediates in “Oligomer” Formation

Charles C. Price* and Joanne Follweiler

*Department of Chemistry, University of Pennsylvania, 231 South 34th Street Philadelphia, PA 19104-6323, U.S.A.


We fully confirm the already convincing evidence presented by Mislow et al. that materials we once identified as “stable thiabenzenes” are oligomers (of unknown structure). We present some experimental observations related to the hypothesis that these oligomers may have formed from reaction of a thiabenzene with phenyllithium through sulfurane-type intermediates.