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Communication | Special issue | Vol 11, No. 1, 1978, pp.187-190
Published online, 1st January, 1970
DOI: 10.3987/S(N)-1978-01-0187
The Oxidative Cyclization of α,β-Unsaturated Ketoximes

Katsuo Kikuchi,* Yuji Maki, Megumi Hayashi, and Noriyuki Murakoshi

*Faculty of Science, Department of Chemistry, Yamagata University


The autoxidation of dibenzalacetone oxime in the presence of several kinds of transition metal salts gave 4-hydroxy-5-phenyl-3-styryl-4,5-dihydroisoxazole, accompanied with cinnamonitrile and benzaldehyde. Similar treatment of benzalacetophenone oxime, benzalacetone oxime and their p-substituted derivatives also afforded 4-hydroxy-4,5-dihydroisoxazole derivatives.