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Communication | Special issue | Vol 18, No. 1, 1982, pp.117-122
Published online, 1st January, 1970
DOI: 10.3987/S(B)-1982-01-0117
A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling

Ei-ichi Negishi,* Fen-Tair Luo, Roger Frisbee, and Hajime Matsushita

*Wetherill Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, U.S.A.

Abstract

The Pd-catalyzed cross-coupling reaction of either heteroarylzinc derivatives with unsaturated organic halides or heteroaryl halides with organometallic reagents containing Zn or Al can produce cleanly and regiospecifically the corresponding carbo-substituted heteroaromatic compounds in high yields.