HETEROCYCLES

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■ Photoamination Directed toward the Synthesis of Heterocyclic Compounds

Masahide Yasuda, Toshiaki Yamashita, Ryuji Kojima, and Kensuke Shima

*Cooperative Research Center, Miyazaki University, Gakuen-Kibanadai, Miyazaki 889-21, Japan

Abstract

This paper reviews the recent author’s studies on the photoamination via electron transfer which were applied to the introduction of the amino group to C-C double bonds of several kinds of the substrates involving arenes, stilbenes, and benzo[a,d]cycloalkenes. The aminated products were used as the precursors for the synthesis of the heterocyclic compounds involving benzylisoquinolines, aporphines, isopavines, dibenzo[a,d]cycloheptenimines, and oxazepines.