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Review | Special issue | Vol 40, No. 1, 1995, pp.441-475
Published online, 1st January, 1970
DOI: 10.3987/REV-94-SR1
■ Transformations of Nitropyrimidines by Action of C-Nucleophiles

Vladimir L. Rusinov, Oleg N. Chupakhin, and Henk C. van Plas

*Department of Organic Chemistry, Ural State Technical University, Mira Str., 19, Ekaterinburg, 620002, Russia

Abstract

The addition of C-nucleophiles to 5-nitropyrimidines, to some of their [1,5-a]pyrazolo- or triazolo-annelated systems, and their subsequent ring transformations have been reviewed. The ring transformations involving the replacement of the N(3)-C(4)-C(5) fragment of the pyrimidine ring, the N(1)-C(5)-C(6), the N(1)-C(2)-N(3) or the N(1)-C(2) fragment by structural parts of different C-nucleophilic agents are summarized; possible pathways, involving these transformations are discussed