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Review | Special issue | Vol 30, No. 1, 1990, pp.719-736
Published online, 1st January, 1970
DOI: 10.3987/REV-89-SR3
Recent Advances in Synthetic Applications of Nitrile Oxide Cycliaddition (1981-1989)

Shuji Kanemasa and Otohiko Tsuge

*Instituete of Advanced Material Study, Kyushu University, 6-1, Kasuga-koen, Kasuga 816-8580, Japan


The synthetic applications of nitrile oxide cycloadditions, developed in the 1980s, are briefly reviewed. Topics discussed in the present review are the modern developments on the generation method of nitril oxides, on the cycloadditions with multiple bonds other than carbon-carbon double and triple bonds, on reductive cleavage of the nitrogen-oxygen bonds of 2-isoxazolines, on the unmasking of functionalities, and on the asymmetric cycloadditions of nitrile oxides.