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Communication | Regular issue | Vol 26, No. 9, 1987, pp.2347-2350
Published online, 1st January, 1970
DOI: 10.3987/R-1987-09-2347
High-pressure Diels-Alder Reactions of 2-Methylthio- and 2-Acetoxyfuran. An Efficient Entry to 4-hydroxycyclohexanones

Hiyoshizo Kotsuki, Yuichiro Mori, Tatsuya Ohtsuka, Hitoshi Nishizawa, Masamitsu Ochi, and Kiyoshi Matsuoka

*Department of Material Science, Faculty of Science, Kochi University, 2-5-1, Akebono-cho, Kochi 780-8520, Japan

Abstract

Diels-Alder reactions of 2-methylthio- and - 2-acetoxyfuran were performed at 15 kbar and room temperature. The adducts were proved to be a useful precursor of 4-hydroxycyelohexanones.