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Paper | Regular issue | Vol 26, No. 7, 1987, pp.1877-1882
Published online, 1st January, 1970
DOI: 10.3987/R-1987-07-1877
Preparation of Synthetically Useful 2-Acyl-1H-imidazoles by an Autooxidation of 1H-Imidazolyl-2-methanol Derivatives

Satoshi Hayakawa, Yoshimi Tamai, Teruyuki Yuasa, Masao Okamoto, and Shunsaku Ohta

*Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 607-8414, Japan


1-Methyl-1H-imidazolyl-2-methanol derivatives (4) were autooxidized in a reaction medium consisting of air, sodium hydride, pyrazole and tetrahydrofuran to give the corresponding 2-acyl-1-methyl-1-H- imidazoles (1) in good yields.