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Communication | Regular issue | Vol 26, No. 7, 1987, pp.1761-1764
Published online, 1st January, 1970
DOI: 10.3987/R-1987-07-1761
Dialkyl Anhydro Sugars in Organic Synthesis. Synthesis of (-)-Invictolide

Takeshi Wakamatsu, Yuji Nishikimi, Hiromi Kikuiri, Hideo Nakamura, and Yoshio Ban

*Faculty of Pharmaceutical Sciences, Hokkaido University, Kita 12 Nishi 6, Kita-ku, Sapporo, Hokkaido 060-0812, Japan


The levorotatory invictolide 1a has been synthesized via the stereocontrolled oxirane ring opening of dianhydro sugars, which are conveniently prepared from levoglucosan(1,6-anhydro-β-D-glucopyranose).