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Communication | Regular issue | Vol 26, No. 5, 1987, pp.1207-1210
Published online, 1st January, 1970
DOI: 10.3987/R-1987-05-1207
Synthetic Studies on Mitomycin I. Synthesis of 7-Methoxymitosene from 6-Methylindole by Selective Oxidation of Benzene Part

Osamu Asano, Shin-ichi Nakatsuka, and Toshio Goto

*Laboratory of Organic Chemistry, Faculty of Agricultures, Nagoya University, Chikusa, Nagoya, Aichi 464-8601, Japan


Synthesis of 7-methoxymitosene 3, one of the mitosene analog containing common carbon skeleton in mitomycin series was achieved in 19 steps from 6-methylindole 4 by oxidative functionalization methods.