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Paper | Regular issue | Vol 26, No. 2, 1987, pp.389-399
Published online, 1st January, 1970
DOI: 10.3987/R-1987-02-0389
The Use of 13C N.M.R. in the Determination of Stereochemistry of 1,2,3-Trisubstituted Tetrahydro-β-carbolines

Patrick D. Bailey and Sean P. Hollinshead

*Department of Chemistry, University of York, Heslington, York YO1 5DD, U.K.

Abstract

The chemical shift of the benzylic carbon of N (2)-benzyl-cis-1,3-disubstituted 1,2,3,4-tetrahydro-β-carbolines is downfield of the corresponding peak of the trans-isomer, and should be valuable, therefore, in the assignment of stereochemistry to these systems.