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Communication | Regular issue | Vol 26, No. 1, 1987, pp.91-94
Published online, 1st January, 1970
DOI: 10.3987/R-1987-01-0091
■ A New Approach to C-9 Hydroxylation of N(6)-Substituted Ellipticine

Albert Langendoen, Gerrit-Jan Koomen, and Upendra K. Pandit

*Organic Chemistry Department, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands

Abstract

6-Methylellipticlne is converted to the corresponding 9-hydroxy derivative via a reaction sequence involving selective C-9 formylation followed by a Baeyer Villiger rearrangement.