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Communication | Regular issue | Vol 26, No. 1, 1987, pp.23-27
Published online, 1st January, 1970
DOI: 10.3987/R-1987-01-0023
■ Novel Intramolecular Nitrogen to Carbon Double Migration

Shekhar Munavalli, Fu-Lian Hsu, and Edward J. Poziomek

*Reearch Directorate, Development and Engineering Center, U.S. Army Chemical Research, Aberdeen Proving Ground, Maryland 21010-5423, U.S.A.

Abstract

Steric hindrance gives rise to an unusual nitrogen to carbon migration when 2-amino-6-methylpyridine is reacted with di-iodomethane at 140-150°C.