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Paper | Regular issue | Vol 24, No. 11, 1986, pp.3115-3128
Published online, 1st January, 1970
DOI: 10.3987/R-1986-11-3115
Attempted Intramolecular Polonovski Cyclisation of an Indole-linked Quinuclidine Derivative — A Novel Intramolecular Oxygen Transfer Reaction

Robert F. Chapman, Norman I. J. Phillips, and Robert S. Ward*

*Department of Chemistry, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.


An attempted modified Polonovski reaction on the indole-linked quinuclidine 8 resulted information of the amide 10 by transfer of an oxygen atom from the quinuclidine N to the indole C-2 position.