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Communication | Regular issue | Vol 24, No. 10, 1986, pp.2793-2796
Published online, 1st January, 1970
DOI: 10.3987/R-1986-10-2793
A Novel 1,2-Alkyl Migration of Trialkyl(4-pyrodyl)borates

Minoru Ishikura, Tsukasa Ohta, and Masanao Terashima*

*Faculty of Pharmaceutical Scicences, Higashinihonngakuen University, 1757 Kanazawa, Toubetu-cho, Ishikari-gun, Hokkaodo 061-0212, Japan


The reaction of lithium trialkyl(4-pyridyl)borates with Lewis acids or acylating agents produced 4-alkylpyridines via 1,2-alkyl migration from boron to pyridine ring.