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Communication | Regular issue | Vol 24, No. 7, 1986, pp.1791-1793
Published online, 1st January, 1970
DOI: 10.3987/R-1986-07-1791
Studies on the Synthesis of Morphinan and Its Related Compounds: New Entry to the Construction of Benzomorphan Ring Skeleton

Tetsuji Kametani,* Masato Nishimura, Yukio Suzuki, and Toshio Honda

*Hoshi University, 2-4-41 Ebara, Shinagawa-ku, Tokyo 142-8501, Japan


Construction of a benzomorphan ring system was achieved by employing phenylselenenyl chloride mediated arene-alkene cyclization and subsequent C-ring formation via an amilynium ion intermediate, as key steps.