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Paper | Regular issue | Vol 24, No. 5, 1986, pp.1331-1346
Published online, 1st January, 1970
DOI: 10.3987/R-1986-05-1331
Synthesis of Optically Active 3-Mercaptopyrrolidine Derivatives. Synthetic Intermediates of Carbapenem RS-533 and Its Isomer

Tomoyuki Shibata, Kimio Iino, and Yukio Sugimura*

*Chemical Research Laboratories and Analytical & Metabolic Research Laboratories, Sankyo Co., Ltd., 1-2-58 Hiromachi, Shinagawa-ku, Tokyo 140-8710, Japan


The optically active 3-mercaptopyrrolidine derivatives(3a, 3b, 4a and 4b), which are synthetic intermediates of the carbapenem RS-533 (2a) and its isomer (2b), were synthesized by convenient and practical methods.