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Communication | Regular issue | Vol 23, No. 10, 1985, pp.2535-2538
Published online, 1st January, 1970
DOI: 10.3987/R-1985-10-2535
■ Polyene Cyclization Teminated by Thiol

Akira Saito,* Hajime Matsushita, and Hajime Kaneko

*Central Reseasrch Institute, Japan Tobacco Inc., 6-2, Umegaoka, Midori-ku, Yokohama, Kanagawa 227-8512, Japan

Abstract

Acid-catalyzed cyclization of geranyl and neryl derivatives was effectively terminated by thiol, and afforded trans- and cis-fused alkyl substituted thiahydrindanes stereoselectively.