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Communication | Regular issue | Vol 23, No. 10, 1985, pp.2525-2529
Published online, 1st January, 1970
DOI: 10.3987/R-1985-10-2525
■ A New Synthesis of (±)-Celacinnine by Means of Non-spermoidine-based Methodology

Toshio Moriwake,* Seiki Saito, Hideaki Tamai, Seiichi Fujita, and Masami Inaba

*Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, Okayama 700-8530, Japan

Abstract

(±)-Celacinnine was synthesized relying on the novel methodology which features nucleophilic ring opening of 2-substituted 5,6-dihydro-4H-1,3-oxazine as a carboxamide synthon and requires neither spermidine nor amino acid condensation process for the lactam framework.