Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 23, No. 9, 1985, pp.2229-2235
Published online, 1st January, 1970
DOI: 10.3987/R-1985-09-2229
N-Vinyl-2-ethoxypyrrolidinimium Tetrafluoborate: A Novel Enophile and Synthetic Equivalent for N-Vinylpyrrolidiniminium

Michael B. Smith* and Hitesh N. Shroff

*Department of Chemistry, U-60, Rm.151, 215 Glenbrok Rd., University of Connecticut, Storrs, CT 06269-3060, U.S.A.

Abstract

Cycloaddition of N-vinyl-2-ethoxypyrrolidiniminium tetrafluoborate, 3, with alkenes, followed by hydride reduction, yields the 8-alkyloctahydroindolizines, 7 and 8 which would be derived from N-vinylpyrrolidiniminium, 2. This cycloaddition-reductive elimination sequence offers a new route to indolizidine type alkaloids.